Marshall R. Metzgar Professor of Chemistry
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2022
“Cleavage of the dimeric heterobimetallic complexes [Pd(dppf)(μ-Cl)]2 [BArF24 ]2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene, BArF24 = tetrakis(bis-3,5-trifluoromethylphenyl)borate) via addition of monodentate phosphine ligands. “ S. A. Wolfarth, N. G. Colicchio, C. S. Nataro, E. W. Reinheimer and C. Nataro, Polyhedron , 2022 , 222 , 115915.
“The postsecondary inorganic chemistry instructional laboratory curriculum: Results from a national survey .” J. R. Raker, J. M. Pratt, M. C. Connor, S. R. Smith, J. L. Stewart, B. A. Reisner, A. L. Bentley, S. Lin and C. Nataro, J. Chem. Educ. , 2022 , 99 , 1971.
“Hydroamination and carboxylative cyclization reactions catalyzed by gold(I) compounds with 1,1′-bis(phosphino)metallocene ligands. . ” N. E. Miner and C. Nataro, J. Organomet. Chem., 2022 , 963 , 122283.
2021
“Synthesis and electronic properties of transition metal complexes containing sulfonamidoquinoline ligands .” M. T. Gole, P. Pauls, S. F. Hartlaub, C. Nataro, L. M. Rossiter, A. R. O’Connor and B. C. Chan, Polyhedron , 2021 , 204 , 115269.
“Synthesis, characterization and electrochemistry of [Pd(PP)MeCl] compounds with 1,1′-bis(phosphino)ferrocene ligands . ” M. E. Hendricks, X. Xu, T. R. Boller, E. M. Samples, A. R. Johnson and C. Nataro, Polyhedron, 2021 , 199 , 115104.
2020
“A community springs to action to enable virtual laboratory instruction .” C. Nataro and A. R. Johnson, J. Chem. Educ. , 2020 , 97 , 3033.
“Hydroamination reactions catalyzed by [Au2 (μ-Cl)(μ-bis(phosphino)ferrocene)][BArF 24 ]. ” S. A. Wolfarth, N. E. Miner, N. E. Wamser, R. K. Gwinn, B. C. Chan and C. Nataro, J. Organomet. Chem., 2020 , 906 , 121049.
“Teaching molecular orbital theory better .” A. R. Johnson and C. Nataro, Advances in Teaching Inorganic Chemistry, Vol. 1 ACS Symposium Series #1370 Ed. by R. M. Jones, 2020 , Ch. 5, p. 47.
2019 2018
“Teaching from the primary inorganic literature: Lessons from Richard Andersen .” J. L. Stewart, A. K. Bentley, A. R. Johnson, C. Nataro, B. A. Reisner and L. A. Watson, Dalton Trans. , 2018 , 47 , 13755.
“Undergraduate research: Contributions to organometallic chemistry. ” C. A. Bradley and C. Nataro, Organometallics , 2018 , 37 , 1813.
“Historical analysis of the inorganic chemistry curriculum using ACS examinations as artifacts .” S. Srinivasan, B. A. Reirsner, S. R. Smith, J. L. Stewart, A. R. Johnson, S. Lin, K. A. Marek, C. Nataro, K. L. Murphy and J. R. Raker, J. Chem. Educ. , 2018 , 95 , 726.
2017
“Literature-based teaching strategies for organometallic courses. ” A. P. Duncan, A. R. Johnson and C. Nataro, Organometallics , 2017 , 36 , 2703.
“Monodentate phosphine substitution in [Pd(κ3 -dppf)(PR3 )][BF4 ]2 (dppf = 1,1’-bis(diphenylphosphino)ferrocene) compounds. ” K. D. Cabrera, A. T. Rowland, J. M. Szarko, P. L. Diaconescu, M. W. Bezpalko, W. S. Kassel and C. Nataro, Dalton Trans. 2017 , 46 , 5702.
“Late transition metal compounds with 1,1ʹ-bis(phosphino)ferrocene ligands. ” S. F. Harlaub, N. K. Lauricella, C. N. Ryczek, A. G. Furneaux, J. D. Melton, N. A. Piro, W. S. Kassel and C. Nataro, Eur. J. Inorg. Chem. 2017 , 424.
2016
“Spectroscopic, structural and computational analysis of [Re(CO)3 (dippM)Br]n+ (dippM = 1,1′-bis(diiso-propylphosphino)metallocene, M = Fe, n = 0 or 1; M = Co, n = 1) .” A. G. Furneaux, N. A. Piro, R. Hernández Sánchez, K. M. Gramigna, N. Fey, M. J. Robinson, W. S. Kassel and C. Nataro, Dalton Trans. 2016 , 45 , 4819.
“Structural, Computational, and Spectroscopic Investigation of [Pd(κ3 -1,1′-bis(di-tert-butylphosphino)ferrocenediyl)X]+ (X = Cl, Br, I) Compounds .” B. L. Blass, R. Hernández Sánchez, V. A. Decker, M. J. Robinson, N. A. Piro, W. S. Kassel, P. L. Diaconescu and C. Nataro, Organometallics . 2016 , 35 , 462.
“Compounds containing weak, non-covalent interactions to the metal in the backbone of 1,1′-bis(phosphino)metallocene ligands .” E. P. Warnick, R.J. Dupuis, N. A. Piro, W. S. Kassel, and C. Nataro, Polyhedron 2016 , 114 , 156.
2014
“X-ray structures and oxidative electrochemistry of phosphine sulfides and phosphine selenides .” M. A. Tiedemann, C. L. Mandell, B. C. Chan and C. Nataro, Inorg. Chim. Acta 2014 , 422 , 193.
“Electrochemical parameterization of 1,1′-disubstituted cobaltocenium compounds .” J. K. Pagano, E. C. Sylvester, E. P. Warnick, W. G. Dougherty, N. A. Piro, W. S. Kassel, and C. Nataro, J. Organomet. Chem. 2014 , 750 , 107.
2013
“Palladium(II) and Platinum(II) Compounds of 1,1ʹ-Bis(phosphino)metallocene (M = Fe or Ru) Ligands with Metal→Metal Interactions. ” K. M. Gramigna, J. V. Oria, C. L. Mandell, M. A. Tiedemann, W. G. Dougherty, N. A. Piro, W. S. Kassel, B. C. Chan, P. L. Diaconescu, and C. Nataro, Organometallics 2013 , 32 , 5966.
“31 P NMR spectroscopy in an undergraduate curriculum.NMR Spectroscopy in the Undergraduate Curriculum ACS Symposium Series #1128 Ed. by D. Soulsby, L. J. Anna and A. S. Wallner, 2013 , Ch. 9, p. 131.
2012
“Synthesis and spectroelectrochemistry of transition metal carbonyls with 1,1′-bis(phosphino)metallocene ligands. ” J. Berstler, A. Lopez, D. Ménard, W. G. Dougherty, W. S. Kassel, A. Hansen, A. Daryaei, P. Ashitey, M. J. Shaw, N. Fey and C. Nataro, J. Organomet. Chem. 2012 , 712 , 37.
2011
“Synthesis and electrochemistry of 1,1′-bis(phosphino)cobaltocenium compounds. ” K.D. Reichl, C.L. Mandell, O.J. Henn, W.G. Dougherty, W.S. Kassel and C. Nataro, J. Organomet. Chem. 2011 , 696 , 3882.
“Electrochemistry of P(CH2Fc)3 and derivatives. ” A.R. Seibert, M.F. Cain, D.S. Glueck and C. Nataro, J. Organomet. Chem. 2011 , 696 , 2259.
2010
“Electrochemistry of FerroTANE and FerroLANE ligands: Free phosphines, metal complexes and chalcogenides. ” C.L. Mandell, S.S. Kleinbach, W.G. Dougherty, W.S. Kassel and C. Nataro, Inorg. Chem. 2010 , 49 , 9718.
“Bis(dialkylaminophosphino)ferrocenes: Reactivity and electrochemistry. ” A.R. Seibert, W.G. Dougherty, W.S. Kassel and C. Nataro, Inorg. Chim Acta. 2010 , 364 , 30.
2009
“Synthesis and Characterization of Transition Metal Complexes Containing 1,1´-Bis(diphenylphosphino)ferrocene (dppf).” C. Nataro and S. M. Fosbenner, J. Chem. Ed. 2009 , 86 , 1412.“1-Methyl-1-vinyl-3,3,5,5-tetraphenylcyclotrisiloxane: An Organofunctional C. Nataro, W. M. Cleaver and C. W. Allen, J. Inorg. Organomet. Polym. 2009 , 19 , 566.“Synthesis, Electrochemistry, and Reactivity of Half-Sandwich Ruthenium Complexes Bearing Metallocene-Based Bisphosphines.” A. P. Shaw, J. R. Norton, D. Buccella, L. A. Sites, S. S. Kleinbach, D. A. Jarem, K. M. Bocage, C. Nataro, Organometallics , 2009 , 28 , 3804.“A New Synthesis and Electrochemistry of 1,1′-bis(b -hydroxyethyl)ferrocene.” K. P. Barry and C. Nataro, Inorg. Chim. Acta , 2009 , 362 , 2068.“Synthesis, Characterization, and Electrochemistry of Compounds Containing 1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene (dppdtbpf).” S. L. Khan, M. K. Breheney, S. L. Martinak, S. M. Fosbenner, A. R. Seibert, W. S. Kassel, W. G. Dougherty and C. Nataro, Organometallics , 2009 , 28 , 2119.
2008
“Taniaphos and Walphos ligands: Oxidative electrochemistry and complexation. Synthesis, characterization, oxidative electrochemistry and X-ray structures of [(Taniaphos/Walphos)MCl2 ] (M = Pd or Pt).” A. F. Maddox, A. L. Rheingold, J. A. Golen, W. S. Kassel and C. Nataro, Inorg. Chim. Acta , 2008 , 361 , 3283.“Synthesis of 1-methy-silaindane and 1-methy-1-germaindane.” D. A. Ruddy, D. H. Berry and C. Nataro, J. Organomet. Chem. , 2008 , 693 , 169.
2007
“When nuclei can not give 100%.” C. Nataro, W. R. McNamara and A. F. Maddox, Modern NMR Spectroscopy in Education ACS Symposium Series #969 Ed. by D. Rovnyak and R. A. Stockland, 2007 , Ch. 18, p. 246.“Electrochemistry and complexation of Josiphos ligands.” B. L. Ghent, S. L. Martinak, L. A. Sites, J. A. Golen, A. L. Rheingold and C. Nataro, J. Organomet. Chem. , 2007 , 692 , 2365.
2006
“Synthesis and electrochemistry of late transition metal complexes containing 1,1′-bis(dicyclohexylphosphino)ferrocene (dcpf). The X-ray structure of [PdCl2 (dcpf)] and Buchwald-Hartwig catalysis using [PdCl2 (bisphosphinometallocene)] precursors.” L. E. Hagopian, A. N. Campbell, J. A. Golen, A. L. Rheingold and C. Nataro, J. Organomet. Chem. 2006 , 691 , 4890.“Anodic Electrochemistry of Free and Coordinated 1,1′-Bis(di-tert -butylphosphino)ferrocene.” F. N. Blanco, L. E. Hagopian, W. R. McNamara, J. A. Golen, A. L. Rheingold and C. Nataro, Organometallics 2006 , 25 , 4292.“Derivatives of 1,1′-bis(diphenylphosphino)ferrocene (dppf): Electrochemistry, Complexation and the X-ray structures of 1,1′-bis(diphenylphosphino)osmocene (dppo) and [PdCl2(dppo)].” S. L. Martinak, L. A. Sites, S. J. Kolb, K. M. Bocage, W. R. McNamara, A. L. Rheingold, J. A. Golen and C. Nataro, J. Organomet. Chem. 2006 , 691 , 3627.
2005
“Synthesis, Structure, and Electrochemistry of an Electron-Rich Chiral Diaminoferrocene, (S,S)-bis(2,5-dimethylpyrrolidinyl)ferrocene.” N. F. Blank, D. S. Glueck, L. N. Zakharov, A. L. Rheingold, M. D. Saybolt, B. L. Ghent, and C. Nataro, Organometallics 2005 , 24 , 5184.“BoPhoz Ligands: Anodic Electrochemistry and Complexes.” B. L. Ghent, L. A. Sites A. L. Rheingold and C. Nataro, Organometallics 2005 , 24 , 4788.“Electrochemistry of di-tert-butylphosphinopentaphenylferrocene (Q-phos) and derivatives.” A. N. Campbell, S. J. Kolb, F. Barrios-Landeros and C. Nataro, Electrochem. Acta 2005 , 50 , 2661.“Anodic Electrochemistry of Ferrocenylphosphine and Ruthenocenylphosphine Chalcogenide Complexes and Lewis Acid Adducts.” B. D. Swartz and C. Nataro, Organometallics 2005 , 24 , 2447.
2004
“The electrochemistry of group VI metal carbonyls containing 1,1′-bis(diphenylphosphino)ferrocene.” A. C. Ohs, A. L. Rheingold, M. J. Shaw and C. Nataro, Organometallics , 2004 , 23 , 4655.“Synthesis and Reactivity of [N(C6 H4 Br)3 ][B(C6 F5 )4 ]. The X-ray Crystal Structure of [Fe(C5 H5 )2 ][B(C6 F5 )4 ].” A. R. O’Connor, C. Nataro, J. A. Golen and A. L. Rheingold, J. Organomet. Chem. 2004 , 689 , 2411.“Determination of the basicity of 1,1′-bis(diphenylphosphino)metallocenes” A. R. O’Connor and C. Nataro, Organometallics , 2004 , 23 , 615.“Lewis Acid-Base, Molecular Modeling and Isotopic Labeling in a Sophomore Inorganic Chemistry Laboratory” C. Nataro, M. A. Ferguson, K. M. Bocage, B. J. Hess, V. J. Ross and D. T. Swarr, J. Chem. Ed. , 2004 , 81 , 722.
2003
“Electrochemistry of late transition metal complexes containing the ligand 1,1′-bis(diisopropylphosphino)ferrocene (dippf).” J. H. L. Ong, C. Nataro, J. A. Golen, and A. L. Rheingold, Organometallics , 2003 , 22 , 5027.“Group 10 metal compounds of 1,1′-bis(diphenylphosphino)ferrocene (dppf) and 1,1′-bis(diphenylphosphino)ruthenocene: a structural and electrochemical investigation. X-ray structures of [MCl2 (dppr)] (M = Ni, Pd)” C. Nataro, A. N. Campbell, M. A. Ferguson, C. D. Incarvito and A. L. Rheingold, J. Organomet. Chem. , 2003 , 673 , 47.“Ruthenium cluster compounds containing 1,1′-bis(diphenylphosphino)ferrocene (dppf): An electrochemical analysis and the crystal structure of [Ru3 (CO)11 ]2 (m -dppf)” A. R. O’Connor, C. Nataro and A. L. Rheingold, J. Organomet. Chem. 2003 , 679 , 72.
2002 2001
“Synthesis and characterization of ferrocenylalcohol derivatives of hexachlorocyclotriphosphazene. X-ray crystal structure of N3 P3 Cl5 OCH2 CH2 C5 H4 FeCp.” C. Nataro, C. N. Myer, W. M. Cleaver, and C. W. Allen, J. Organomet. Chem. , 2001 , 637-639 , 284.“Analysis of phosphines functionalized with crown ether groups by NMR and cyclic voltammetry.” C. Nataro, H. M. Baseksi, C. M. Thomas, B. J. Wiza and K. M Rourke, Polyhedron 2001 , 20 , 1023.
1999 1998 1997
